Chemistry

AI finds the first stars ✨were not alone, Auto-switch for large electronic devices, A metabolite against autoimmune diseases, & Converting fruit waste 🍊🍉into solar stills. Plus in our blog: A career worth doing, a life worth living. Read all in the latest Editor's Choice.

We sat down with Dr. Ji Ha Lee to get to know her and her work on developing recyclable and degradable gels that can replace plastics as well as nanogels that can help with targeted drug delivery.

- Development of low-temperature, highly graphitized carbon synthesizing method that can overcome the limitations of existing fuel-cell carbon supports - Expected to be used in next-generation fuel-cell vehicles with improved generation efficiency and excellent stability - Study results will be published in ‘Applied Catalysis B: Environmental’, a top journal in the field of Environmental Science

- The world’s first technology for synthesizing high-quality and low-cost copper-graphene nanowire using intense scintillation - Implementation of high-performance transparent-flexible electronic device based on copper-graphene nanowire and publication in the international journal Nano Energy, which is renowned in the field of energy

Osaka Metropolitan University scientists have developed a process using artificial photosynthesis to successfully convert more than 60% of waste acetone into 3-hydroxybutyrate, a material used to manufacture biodegradable plastic. The results were obtained using low-concentration CO2, equivalent to exhaust gas, and powered by light equivalent to sunlight for 24 hours. The researchers expect that this innovative way of producing biodegradable plastic could not only reduce CO2 emissions but also provide a way of reusing laboratory and industrial waste acetone.

An Osaka Metropolitan University joint research group has discovered that near-infrared absorbing dyes, which had previously been considered to have closed-shell electronic structures, have an intermediate electronic structure, between closed- and open-shell structures. They also found that as the wavelength of near-infrared light that can be absorbed becomes longer the contribution of open-shell forms increases within the dye. These newly discovered characteristics are expected to be utilized to develop new near-infrared absorbing dyes that can absorb longer wavelength near-infrared light.

Scientists in Singapore converted fruit waste into a solar absorber called Mxene to develop an efficient and sustainable water desalination process.

A research team has highlighted recent achievements in antiferromagnetic spintronics in a review article, unearthing a new frontier in the field.

Researchers at Kanazawa University report in JACS Au how they have developed operando scanning ion conductance microscopy to allow simultaneous measurements of changes in the anode surface topography of a lithium ion battery during use, as well as the varying ion concentration with depth. Combining both types of information should help researchers evaluate the correlation between the two to design better batteries.

An international interdisciplinary team of researchers hailed from India, Malaysia, Singapore and Thailand has successfully developed a method of using chitosan from terrestrial insects to manufacture eco‐friendly polymer composite parts using the 3D printing method.

Researchers at Kanazawa University report in ACS Nano how high-speed atomic force microscopy can be used to study the biomolecular mechanisms underlying gene editing.

Osaka Metropolitan University scientists successfully quantified the total reactive polysulfide content of 22 different types of vegetables, including onions and garlic. They also revealed that reactive polysulfides are not only found in the leek genus (Allium), such as onions and garlic but also in the cruciferous family of vegetables (Brassicaceae), such as broccoli and cabbage.

The first-ever molecular catalyst specifically tailored for mechanochemical reaction conditions enables high-efficiency transformations at near room temperature.

Moving parts in mechanical come into regular contact, leading to wear and tear. Now, researchers at Tohoku University have developed a contact control system, driven by artificial intelligence, to greatly reduce contact between damaged parts.

Researchers at Kanazawa University report in Nano Letters the discovery of a biomolecular dynamical process likely relevant to gene expression. The process, revealed by means of high-speed atomic force microscopy, involves DNA and its packaging molecules.

A collaborative research group from Tohoku University and the Toyohashi University of Technology has invented a new and efficient method to create metallic plasmas from solid metals under a strong magnetic field in a microwave resonator.

Scientists from Oil Crops Research Institute (OCRI) of Chinese Academy of Agricultural Sciences (CAAS), Anhui Agricultural University (Anhui, China), Newcastle University in Singapore, and Huizhou Comvikin Biotechnology Co., Ltd (Guangdong, China) have developed a green and efficient approach to synthesize highly liposoluble and antioxidant L-ascorbyl esters by immobilized lipases.

Researchers from Osaka Metropolitan University have developed principles and technologies of nanofluidic devices to freely manipulate nanomaterials, biomaterials, and molecules at the single-molecule level using fundamental technologies such as nanofluidic processing, functional integration, and fluidic control and measurement, which has pioneered the way to integrate various fields under nanofluidics.

Researchers at Kanazawa University report in Angewandte Chemie International Edition how the formation and deformation speed of interlocked molecular structures called rotaxanes can be tuned — a discovery that may lead to an enhanced functionality of rotaxanes as building blocks for molecular machines.

Tree rings forecast extreme weather in central Asia, Squid 🦑and chemistry make versatile hydrogels, James Webb telescope reveals the earliest galaxies & Reducing negative effects of screen time. Read all in the latest Editor's Choice. Plus our latest journalist resource "Experts for Media: Antimicrobial Resistance "🦠.

Amide bonds are important functional groups in medicinal chemistry and account for roughly 16% of all reactions performed in drug-discovery research. Some amide bond reactions using pharmaceutically important nitrogen-containing heterocyclic compounds, such as indole, carbazole and pyrrole, rather than amines are not efficient using conventional production methods. In a recent study, a team of leading chemists developed a novel one-pot reaction to efficiently form amide bonds using low-reactivity, nitrogen-containing heterocyclic compounds and carboxylic acid without special equipment or heat.

- Elastic Triboelectric Tactile Sensor Development Using Graphene Electrode Unaffected by Elasticity - Published in 'Nano Energy' as a Technology to Produce Precise Sensors by Supplementing the Output Change Problem of Sensors Deformed by Human Activity

Hokkaido University researchers have developed a novel method to design and develop peptide antibiotics in large numbers, which will prove critical to controlling antibiotic resistance.

Two catalysts working in tandem enable inexpensive formate salts to perform difficult dearomative reactions, giving products potentially useful for drug development.

Researchers from Osaka University expanded the synthetic toolkit for preparing valuable chemical precursors from renewable feedstocks. They used microwave irradiation to dramatically improve the selectivity of the formose reaction, forming a simple six- and seven-carbon mixture that can be readily purified. These findings will help the chemicals industry minimize the use of fossil resources and improve the sustainability of manufacturing processes.

Traditional hydrogen peroxide production is energy and emission intensive, and so scientists have sought to synthesize it electrochemically. But tailoring the cobalt-nitrogen-carbon (Co-N-C) catalyst has been challenging. Using a theoretical prediction, which was then experimentally verified, an international research group has designed a Co-N-C catalyst that alleviates this problem.

Researchers used a chemical synthesis robot and computationally cost effective A.I. model to successfully predict and validate highly selective catalysts.

Researchers from Osaka University have used single carbon atom doping to form four chemical bonds in one step. Gamma-lactams (cyclic molecules that are common in antibiotics) were easily synthetically accessible from alpha, beta-unsaturated amides (an important molecule in cancer progression). The team chemically modified an anti-seizure medication in 96% yield, highlighting the work's utility to otherwise synthetically complex aspects of pharmaceutical development. The results of this work could become foundational to drug discovery and development.

Researchers from Osaka University have shown that a system known as the GET pathway is essential for efficient mitophagy, the process by which mitochondria are removed from cells. The GET pathway targets a protein assembly called the Ppg1–Far complex, which inhibits mitophagy, to the membrane of a part of the cell called the endoplasmic reticulum. When the GET pathway is defective, this complex instead becomes targeted to mitochondria, where it acts to suppress mitophagy.

Everyday electronics, such as our phones, employ surface acoustic wave devices for frequency filtering and sensing. But this consumes a lot of energy, serving as a drain on battery life. Now, a team of researchers has developed a new acoustic waveguide based on the mathematical concept of topology, which will help alleviate this problem.